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You can still do it, just don't get sexual unless they go there first. What you do is become very friendly and interested in what they have to say. Give them attention and build rapport. And much like you would in a normal set, try to throw out a closing comment at a high point. Like mention hanging out or getting in touch again. Ask if she is on Facebook so you can send her a link to whatever thing you were talking to her about that she seemed interested in.
The mistake most guys make is not building rapport and being too forward and trying to close too aggressively. Besides, what job fires someone because they asked a customer if they were on Facebook?
No to this.
I agree with Jack on dont hit on women at work if it risks your career. I'd even say, you CAN meet women from your job, but not in the way above. You have to be way more passive than you'd be outside of work. Either you're an attractive guy and a simple conversation facilitates a date or meet up or you're not. If you're "building" attraction at work, then you shouldnt "game" there. If you're attractive, not just physically, be friendly and some chicks will give you clear hints they want to talk or meet outside of work. You want to go there, do your job, chat if she's chatting and ACCEPT a suggestion to hang out. Not INITIATE. Too easy to read a wrong signal and get complaints. Don't PUSH a conversation when a chick already may feel vulnerable with you in her place. If you're asking for a number/facebook or whatever, it should be after she has said we should hang out. This is just if you really want to so you minimize the risk. If you dont push conversations or ask for contact details unwarranted you wont get complaints.