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It's not too relevant I don't think, but I was her first.
Of course that is relevant. She can't orgasm because she WANTS to orgasm too badly. Wanting to orgasm creates pressure, but she needs to be completely relaxed to orgasm, and that means having no pressure.
A good way to overcome this is to have sex at night, of course she fails to orgasm, but you keep sleeping together, then wake her up in the night and start having sex again...the second time there is much less pressure because she already conceded she wasn't going to orgasm that night, and she's also in a dreamy state which makes her more comfortable.
The good news is that once you break through the barrier, it will become easier and easier for her to cum, and once she gets in the habit of doing it with you, it will come just as easily and naturally as it is for a guy to cum when he's masturbating alone.
Good luck