For people who say 'nice guys finish last.' Wrong.
Guys who aren't their own person finish last. I should know, I was one of them. They put women on pedestals and admire them constantly, ignoring and neglecting themselves, bending over backwards for them. Most women of value are used to this, and guess what, its low value and it bores them.
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What's the shit with being a nice guy when picking up girls? Do I need to become more of a dickhead and how?
You're focusing on the wrong thing, most likely because of the popular 'nice guy' misconception. She didn't friend-zone you because you're nice and "down to earth", I can guarantee that. Those are actually good qualities. She friend-zoned you because your interactions with her didn't interest her sexually, at least not enough to get her into bed. Maybe you bored her by doing what most guys do ("Oh, wow, you're beautiful. May I take you to dinner? Please, come off your pedestal for 10 minutes to talk to me, my life sucks"), maybe you bugged her too much and were too available, etc, I don't know, without more specifics I won't be able to tell you, (put more info next time), but I know she didn't friend-zone you simply because she smelt 'nice' off of you.
You can be a nice person and get the girl. The vast majority of PUAs I know prove that.
Being 'more of a dickhead' is the wrong way to put it, Sidd. If the problem was, for example, that you were too available, always talking to her whenever you had the chance/calling her too much, being less available doesn't make you a dickhead. (Dickhead is a collection of strong negative qualities). Again, we need more from you for better answers to your problems.