What you're describing is the psychological and economical principle of scarcity --
http://www.taooftalk.com/home/2011/7/16 ... uable.html -- as the supply of something increases, the price per unit decreases, as there is more of it to go around. Water is free because it is the most common substance on earth. However, as the scarcity of something increases, its demand and price increases, because it is more rare.
What you are describing is the psychological portion of this principle. You don't want girls that you can have because they are easy to acquire, and you want to pursue women that aren't as easily as attainable -- even moreso the girls that you can't have, as it sounds like you are getting an infatuation with a girl who could very well already have a boyfriend.
Your self esteem fluxuates from day to day, that also isn't something specific to you -- everyone gets caught up inside themselves from time to time. There is, unfortunately, no "magic pill" you can take to make yourself not shy (Well, maybe Extacy, but I don't think that's what you're looking for.) -- I would recommend opening everyone in the Library who doesn't seem to be studying too hard. Find out what that girl or guy across from you is reading -- "Hey, one of my friends heard that book is cool, could you comment on it?" Boom. There's your opener. The more conversations you have, the looser you become, and the easier it becomes to *genuinely* (Not Run Game on.) converse with the attractive women you meet.
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