| Depends on the situation, but if I approach a group in crowded, loud bar or club, I try to single one out, approach her, and eventually have her introduce me to her friends. Women accept the fact that their friends will be approached, and it's normal in a loud place to only talk with one out of the group, but it's weird to not introduce yourself eventually so you gotta do that.
If it isn't possible to single out one, whether she's physically situated in a place where you'd have to walk through the group to talk to her, or any other reason it may be socially awkward, I approach the whole group as if it were 1 person. Eventually, one of them will single herself out by being the loud talkative one. If it's the girl you want, fine. If not, you want to eventually work her into the conversation by asking her opinions and focusing on her, trying to make a connection without alienating the rest. Following that, you have to isolate her, and in both scenarios that requires making her feel comfortable with you, and making the group comfortable with letting her go as well.
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