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Dude, personally it's become one of my rules to never hook up with the "alternative" type. I'm a punk, so I hang around those sort of places before I was even allowed to buy a drink at the bar legally... There are a lot of them that just dress and act that way cause it's "cool" the ones that really live that shit are completely fucked in the head. Honestly, just treat them like any other girl, you'll come right. You'll get a lot of shit tests though cause they only want the hardest punk or whatever, so be prepared for that. I once had a girl punch me through the face and ask if I still wanted to fuck her afterwards... It's gets strange out there!
Oh man, this brings back a lot of memories! I currently live in a part of the world where there is no "scene" and no alt girls, but I was goth before the subculture really existed and spent a lot of years both scoring and failing with these girls--mostly failing early on, mostly scoring later on.
One difference is that a good percentage of alt/goth/emo/punk girls are explicitly and openly into some form of fetish, e.g. bdsm, bondage, D/s, etc. I personally have no problem with that, but the trick is that you have to sort the fetishists from the "stylists"--who are not down with that.
A couple of things you might try...
With a punk girl esp., put the palm of your hand against her shoulder and push (don't shove), but hard enough to move her, and say, "Get the fuck off of me, I'm not that easy." Say it like it both is and isn't a joke. She may retaliate physically... be ready for that.
With a goth girl, look directly at her for about 10 seconds, not hostile, just a focused, interested, observant gaze. If she looks away and then looks back say, "No, I don't think I'll tell you," then turn away. If (when!) she tries to to get you to "tell me what," refuse with knowing smile, at most say, "later." If she starts poking or otherwise taking it physical, take her by the wrist and draw her up close to you.
Both of these are inviting her to escalate. They work.